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2 article(s) from Yamago, Shigeru

Enhanced host–guest interaction between [10]cycloparaphenylene ([10]CPP) and [5]CPP by cationic charges

Eiichi Kayahara,
Yoshiyuki Mizuhata and
Shigeru Yamago

Beilstein J. Org. Chem. 2024, 20, 436–444, doi:10.3762/bjoc.20.38

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Graphical Abstract

Figure 1: Structures of a) [10]CPP⊃C₆₀, (b) [n+5]CPP⊃[n]CPP, and (c) [10]CPP⊃[5]CPP²⁺ (this work).

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Figure 2: ¹H NMR spectra (CD₂Cl₂, 25 °C) of a) a mixture of [8]–[12]CPPs and [5]CPP²⁺[B(C₆F₅)₄⁻]₂ before and aft...

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Figure 3: Cyclic voltammograms of [10]CPP⊃[5]CPP²⁺[B(C₆F₅)₄⁻]₂, [10]CPP, and [5]CPP²⁺[B(C₆F₅)₄⁻]₂ in Bu₄N⁺ B(C...

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Figure 4: UV–vis–NIR spectra of [10]CPP⊃[5]CPP²⁺[B(C₆F₅)₄⁻]₂ (black), [10]CPP (blue), and [5]CPP²⁺[B(C₆F₅)₄⁻]₂...

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Figure 5: Top and side view of [10]CPP⊃[5]CPP²⁺ complexes a) 1, b) 2, and c) 3 obtained by DFT calculation at...

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Figure 6: HOMO−1, HOMO, LUMO, and LUMO+1 orbitals of [10]CPP⊃[5]CPP²⁺ (1), [5]CPP²⁺, and [10]CPP.

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Figure 7: X-ray crystal structure of [10]CPP⊃[5]CPP²⁺[B(C₆F₅)₄]₂. a) Side and b) top views of ORTEP drawings....

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Supp Info

Letter

Published 23 Feb 2024

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Organotellurium-mediated living radical polymerization under photoirradiation by a low-intensity light-emitting diode

Yasuyuki Nakamura and
Shigeru Yamago

Beilstein J. Org. Chem. 2013, 9, 1607–1612, doi:10.3762/bjoc.9.183

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Graphical Abstract

Figure 1: UV–vis absorption spectra of organotellurium chain transfer agent 1 and dimethyl ditelluride in tol...

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Scheme 1: Photopolymerization in the presence of organotellurium chain transfer agent 1.

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Figure 2: GPC traces for the polymerizations of MMA (Table 1). The percentages in the legend refer to the ND filters...

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Scheme 2: Activation and deactivation mechanism of dormant (P-TeMe) and ditelluride.

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Figure 3: Experimental setup for the photopolymerization using the LED.

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Full Research Paper

Published 07 Aug 2013

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